I wanted to find out what PF_BOUNCER_ENABLED does, but it's not listed on https://docs.pixelfed.org/running-pixelfed/configuration.html
There might be others.
As an icing on the cake, documentation could be shown on /i/admin/diagnostics/home too.
Maybe it's possible to find a format so that the documentation can be generated from the code? Keeping it close to the code will make it easier not to forget documentation of new parameters.